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Key Equations and Concepts in this chapter
Chemical Reactions
Parts of this equation/concept include:
| A. Identifying Reaction
Type |
This chapter discusses three types of reactions: oxidationreduction
(redox), acidbase, and precipitation.
>> Calculating Oxidation Numbers
Oxidation number rules. (Consider each ion of an ionic compound
separately.)
- The sum of all oxidation numbers in any compound or ion is
equal to its charge. Therefore
- The oxidation number of a pure element is zero.
- The oxidation number of a monoatomic ion is equal to its
charge.
- The oxidation number of hydrogen is
- +1 if combined with a nonmetal
- 1 if combined with a metal
- 0 if combined only with itself
- The oxidation number of oxygen is 2 (unless that contradicts
rule 1 or 2).
>> Example 1
What is the oxidation number of each element in the following
examples?
| a. Ca(ClO4)2 |
b. K2Cr2O7 |
c. PH3 |
d. Br2 |
e. LiH |
 |
 |
 |
 |
 |
Solution:
- Since this is an ionic compound, it will be easier to consider
each ion separately. The two ions that make up this compound
are Ca2+ and ClO4.
That there are two ClO4 ions is not needed
to calculate the oxidation numbers.
As monoatomic ion, the oxidation number of calcium is equal
to the charge = +2.
The oxygen in ClO4 is assigned an oxidation
number of 2, since there is no contradictory rule. The
oxidation number of the chlorine is determined using the rule
that the sum of the oxidation numbers must equal the charge.
Cl + 4(2) = 1
Cl = +7
- This is also an ionic compound of K+ and Cr2O72.
The potassium will have an oxidation number equal to its charge,
+1. The oxygen will have an oxidation number of 2, since there
is no contradictory rule. The chromiums, since they are in the
same atom, must have the same charge and can be determined from
the “sum of the oxidation numbers equals the charge”
rule.
2Cr + 7(2) = 2
Cr = +6
- This is a molecular compound, so it cannot be divided into
ions. Since hydrogen is combined with a nonmetal, it will have
an oxidation number = +1. Using the summing rule,
P + 3(+1) = 0
P = 3
- Bromine is an uncombined element. Therefore its oxidation
number is zero.
- There are two ways to approach this. If you divide it into
its component ions, Li+ and H, the oxidation
number is equal to the charge. You could also note that hydrogen
is combined with a metal, so its oxidation number = 1 and the
summing rule makes lithium = +1.
>> Identifying Redox Reactions
Oxidationreduction (redox) reactions are characterized by
changes in oxidation numbers. However, it is often possible to notice
that oxidation numbers are changing without actually calculating
them. Some clues that redox is occurring are the following:
- An element that is uncombined (with any different element) on
one side of the reaction and combined on the other.
- The number of oxygens or hydrogens associated with element changes.
- The charge on the element changes
Sometimes it is easier to spot that a reaction is not a redox reaction.
Nonredox reactions (which include acidbase and precipitation
reactions) are often characterized by reactants that each come as
two pieces (like HCl with pieces of H+ and Cl
or K2SO4 with pieces of K+ and
SO42) and the pieces of the two reactants
stay the same but are rearranged in the products.
>> Example 2
Characterize the following reactions as redox or nonredox.
- 2 HCl + Mg
H2
+ MgCl2
- HCl + AgNO3
HNO3 + AgCl
- KMnO4 + 5 FeCl2 + 8 HCl
5
FeCl3 + MnCl2 + 4 H2O + KCl
Solution:
- Redox reaction. The magnesium was alone as a reactant and
was combined with chlorine as a product. Hydrogen was combined
as a reactant and was uncombined as a product.
- Nonredox reaction. The pieces here are H+, Cl,
Ag, and NO3. None of the
pieces change; they are just rearranged.
- Redox. First, remember that if you can spot one change, it
must be redox. If that is all the question asks, you can stop
there. Don't get distracted by the extras.
Notice the iron. It changes charge! In the reactants it has two
Cl ions, so it must have a +2 charge, but in the products
there are three Cl ions, so the charge is +3.
Notice the manganese. It is combined with four oxygens in the
anion but is combined with Cl in the products. The
change in number of oxygens is a tip-off. So is the fact that
it switched from the anion position to the cation position. Obviously,
this is not just a simple rearrangement.
>> Identifying AcidBase Reactions
Acidbase reactions require both an acid and a base as reactants.
(Products are irrelevant!) Many other types of reactions include
one or the other. For it to be acidbase it must have both.
Acidbase reactions are sometimes called proton-transfer
reactions because an H+ moves from the acid to the base.
If you can spot this happening, even with nontraditional acids and
bases, it will still be an acidbase reaction.
>> Example 3
What is the acid and the base in the following acidbase
reaction?
HCN + HPO42
CN + H2PO4
Solution:
HCN is the acid. It loses that first hydrogen when it becomes
CN. Notice that the charge also changes.
HPO42 is the base. It gains a hydrogen
and the charge increases by 1.
Traditional acids are easily identified from the formula. When
hydrogen is the first element, it is an acid. If the formula is
written this way, all hydrogens at the beginning of the formula
will react with the base. There are two important exceptions:
H2 and H2O. H2 is never an acid.
Although water is not normally considered an acid, in some cases
it can act as one. If it does, it will lose only one proton. In
fact, you may often find it advantageous to think of the formula
of water as HOH, since it normally reacts as H+ and
OH.
Another traditional way to write organic (carbon-based) acids
is to have the formula end in “COOH.” If the formula
is written this way, there will probably be lots of hydrogens,
but only the one after the COO is acidic.
Two types of common bases are discussed in this chapter, hydroxides
(OH) and carbonates (CO32).
These are both anions. In reactions each will be associated with
a cation. The cation will not affect its basic properties. When
hydroxides react with an acid, one product will be water. When
carbonates react with an acid, the products will include carbon
dioxide and water.
>> Example 4
Determine if the following are acidbase reactions. If
so, identify the acid and the base.
- 2 HBr + K2CO3
H2O
+ CO2 + 2 KBr
- FeI2 + 2 NaOH
Fe(OH)2
+ 2 NaI
- H2S + Ni(OH)2
2
H2O + NiS
- Sr(OH)2 + C6H5COOH
H2O
+ Sr(C6H5COO)2
Solution:
- It is acidbase. The HBr is the acid, hydrogen first.
The K2CO3 is the base, a carbonate.
- It is not acidbase. The NaOH is a base, but
FeI2 is not an acid.
- This is acidbase. H2S is the acid; two acidic
hydrogens begin the formula. Ni(OH)2 is the base,
a hydroxide.
- This is acidbase. Sr(OH)2 is the hydroxide-type
base. C6H5COOH is the organic acid. Notice
that only the hydrogen at the end has moved in the product formula.
>> Identifying Precipitation Reactions
Precipitates are solids that form from a chemical reaction. Therefore
a precipitation reaction makes a solid product. This is almost always
an insoluble salt. To determine whether or not a salt is soluble,
you need to learn the solubility rules in Table 5.4. Solubility
rules work only for ionic compounds (salts). If the product is not
ionic, you may assume (for this chapter) that it is not a precipitate.
Precipitates can form in any type of reaction. However, if a precipitate
forms as part of a redox reaction, the redox part is more important
than the precipitation. Therefore such reactions are normally classified
only as redox reactions and not as precipitation reactions. On the
other hand, it is quite common to classify a reaction as both acidbase
and precipitation.
>> Example 5
Determine whether or not the following reactions are precipitation
reactions. If they are, what is the precipitate?
- 2 HBr + K2CO3
H2O
+ CO2 + 2 KBr
- FeI2 + 2 NaOH
Fe(OH)2
+ 2 NaI
- H2S + Ni(OH)2
2
H2O + NiS
- 2 KCl + I2
2
KI + Cl2
- Na2CO3 + Ca(OH)2
CaCO3
+ 2 NaOH
Solution:
Don't worry about the reactants, a precipitate is a product.
- This is not a precipitation reaction. Water and carbon dioxide
are molecular compounds; KBr is soluble.
- This is a precipitation reaction. The precipitate is iron(II)
hydroxide. Sodium salts are always soluble.
- This is a precipitation reaction. The precipitate is NiS.
- This is not a precipitation reaction. It is redox. Did you
notice the iodine and chlorine combining and uncombining?
- This is a precipitation reaction. Calcium carbonate is the
precipitate.
| B. Balancing
Redox Reactions and Identifying Oxidation and Reduction Processes |
When balancing redox reactions, it is useful to divide them into
half-reactions. To divide the reaction, you must determine the two
elements that change oxidation state. This can be done by determining
the oxidation number of each element or by using the other clues
discussed in the section on identifying redox reactions. Each half-reaction
will contain one element changing oxidation state. You should write
the reactant containing the element changing oxidation state on
the reactant side, the product containing the same element in a
different oxidation state on the product side. (They are called
skeletal half-reactions.) There should be two of these reactions.
Balance the skeletal half-reactions using the following steps.
For acidic, aqueous solutions:
- Balance all elements except hydrogen and oxygen.
- Add H2O to balance water.
- Add H+ to balance hydrogen.
- Add electrons (e) to balance charge.
For basic, aqueous solutions:
- Balance all elements except hydrogen and oxygen.
- For each oxygen needed, add 2 OH to that side and
one H2O to the other side.
- For each hydrogen needed, add one H2O to that side
and one OH to the other side.
- Add electrons (e) to balance charge.
These are the balanced half-reactions. The half-reaction that loses
electrons is the oxidation. In that half-reaction, the electrons
will be a product and the reactant-changing oxidation state will
be the reducing agent. The half-reaction that gains electrons is
the reduction. In that half-reaction, the electrons will be a reactant
and the reactant containing the element-changing oxidation state
is the oxidizing agent.
To add the half-reactions together, each must have the same number
of electrons. The steps continue the same for both acidic and basic
solutions.
- Multiply each stoichiometric coefficient of either (or both)
reactions to obtain the least common multiple of electrons.
- Add the two reactions together, keeping all reactants on the
reactant side and products on the product side.
- Simplify by canceling compounds that are the same on each side
of the reaction. Hints: (a)
If electrons don't cancel, you did it wrong. (b)
Stoichiometric coefficients are number of compound not part of
the formula; thus it is perfectly appropriate for 3 H+
+ OH
2
H+ + H2O to become H+ + OH H2O.
>> Example 6
Balance the following redox reaction in acidic solution. Identify
the oxidation half-reaction, the reduction half-reaction, the
oxidizing agent, and the reducing agent.
U4+ + MnO4 UO22+
+ Mn2+
Solution:
Uranium and manganese are changing oxidation states so the skeletal
reactions are
U4+ UO22+
MnO4 Mn2+
- Every element except oxygen is already balanced.
- Add water to balance oxygen:
U4+ + 2 H2O UO22+
MnO4 Mn2+
+ 4 H2O
- Add H+ to balance hydrogen (which is now unbalanced
due to the addition of water):
U4+ + 2 H2O UO22+
+ 4 H+
MnO4 + 8 H+ Mn2+
+ 4 H2O
- Add electrons to balance charge. (Just add up the charges
on ions, multiplied by their coefficients. Remember that balance
is the same, not zero.) For the uranium half-reaction, charge
on the reactants = +4; charge on the products = +6. For the
manganese half, charge on the reactants = +7; charge on the
products = +2
U4+ + 2 H2O UO22++
4 H+ + 2 e
MnO4 + 8 H+ + 5 e Mn2+
+ 4 H2O
These are the balanced half-reactions. The one for uranium is
the oxidation reaction and U4+ is the reducing agent.
The one for manganese is the reduction reaction and MnO4
is the oxidizing agent.
- Multiply reactions to get the least common multiple of electrons.
The least common multiple of electrons in this example is 10.
So the uranium half will be multiplied by 5 and the manganese
half by 2.
5 U4+ + 10 H2O 5
UO22+ + 20 H+ + 10 e
2 MnO4 + 16 H+ + 10 e 2
Mn2+ + 8 H2O
- Add the two reactions together:
5 U4+ + 10 H2O + 2 MnO4
+ 16 H+ + 10 e
2
Mn2+ + 8 H2O + 5 UO22+
+ 20 H+ + 10 e
- Simplify:
5 U4+ + 2 H2O + 2 MnO4 2
Mn2+ + 5 UO22+ + 4 H+
It's scary, but this is usually the easiest and most consistent
way to balance redox reactions.
>> Example 7
Balance the following redox reaction in acidic solution. Identify
the oxidation half-reaction, the reduction half-reaction, the
oxidizing agent, and the reducing agent.
Cu + NO3 Cu2+
+ NO2
Solution:
Copper and nitrogen are changing oxidation state, so the skeletal
reactions are
Cu Cu2+
NO3 NO2
- All elements except oxygen are balanced.
- The oxygen is balanced for copper (at zero) so that is unchanged,
but the nitrogen needs one:
Cu Cu2+
NO3 NO2+
H2O
- Now we have to balance hydrogen on the nitrogen reaction;
copper is still fine.
Cu Cu2+
NO3 + 2 H+ NO2+
H2O
- Now electrons: for copper, the reactant side charge = 0 and
the product side charge = +2; for nitrogen the reactant side
charge = +1 and the product side charge = 0.
Cu Cu2+
+ 2 e NO3 + 2 H+
+ e NO2+
H2O
These are the balanced half-reactions. The copper reaction represents
oxidization and copper is the reducing agent. The nitrogen half
represents reduction and nitrate ion is the oxidizing agent.
- Determine the least common multiple of electrons (it's 2)
and multiply the reactions so that each has that many electrons.
The copper reaction is fine; the nitrogen must be multiplied
by 2.
Cu Cu2+
+ 2 e 2 NO3 + 4 H+
+ 2 e 2
NO2+ 2 H2O
- Add the reactions:
Cu + 2 NO3 + 4 H+ + 2 e 2
NO2+ 2 H2O + Cu2+ + 2 e
- Simplify:
Cu + 2 NO3 + 4 H+ 2
NO2+ 2 H2O + Cu2+
Done!
>> Example 8
Balance the following redox reaction in basic solution. Identify
the oxidation half-reaction, the reduction half-reaction, the
oxidizing agent, and the reducing agent.
S2O62 + TeO32 SO42
+ Te
The elements changing oxidation state are sulfur and tellurium,
so the skeletal half-reactions are
S2O62 SO42
TeO32 Te
- Sulfurs aren't balanced! This is an easy step to forget because
you don't need it all that often.
S2O62 2
SO42 TeO32 Te
- Balance oxygens with hydroxide and water…. It's basic
conditions! For sulfur there are six oxygens on the reactant
side, eight on the product side; for tellurium there are three
oxygens on the reactant side, none on the product side.
S2O62 + 4 OH 2
SO42 + 2 H2O TeO32
+ 3 H2O Te
+ 6 OH
- The hydrogens are balanced. It's an advantage of this method,
no backtracking as with acids.
- Balance charge. For sulfur the reactant side charge = 6,
the product side charge = 4. For tellurium, the reactant side
charge = 2, the product side charge = 6.
S2O62 + 4 OH 2
SO42 + 2 H2O + 2 e
TeO32 + 3 H2O + 4 e Te
+ 6 OH
With these balanced half-reactions, the sulfur half-reaction
is the oxidation with S2O62
acting as the reducing agent. The tellurium reaction is the reduction
and TeO32 is the oxidizing agent.
- Use the least common multiple of electrons; in this case LCM
= 4.
2 S2O62 + 8 OH 4
SO42 + 4 H2O + 4 e
TeO32 + 3 H2O + 4 e Te
+ 6 OH
- Add:
2 S2O62 + 8 OH
+ TeO32 + 3 H2O + 4 e Te
+ 6 OH + 4 SO42 + 4 H2O
+ 4 e
- Simplify:
2 S2O62 + 2 OH
+ TeO32 Te
+ 4 SO42 + H2O
Done!
>> Predicting the Products of AcidBase
Reactions
The products of an acidbase reaction are mostly determined
by following the acidic proton from the acid.
When the acid loses its proton (or protons), an anion will remain.
The proton will combine with the base. Two common bases are hydroxide
and carbonate.
>>> Hydroxide Bases
If the acidic proton combines with a hydroxide, the product is
water:
H+ + OH H2O
(HOH)
However, the hydroxide was probably combined with a cation as a
reactant. This cation will combine with the leftover anion from
the acid to make a salt. Remember, the ratio of cation to anion
must be the smallest ratio that results in an overall zero charge.
>> Example 9
Predict the products for the reaction of HCl with Ca(OH)2.
Solution:
The anion left over from the acid is Cl. The cation
associated with the hydroxide is Ca2+. Therefore when
they combine it will be CaCl2. You need one hydrogen
for each hydroxide, but that will happen in the stoichiometric
coefficient. The formula cannot be changed. Thus the reaction
is
2 HCl + Ca(OH)2 2
H2O + CaCl2
>>> Carbonate Bases
It requires two acidic protons (2 H+) to react with
each carbonate (CO32). Combining these gives
H2CO3, carbonic acid. As it turns out (and
this is rather surprising), carbonic acid is unstable. Normally,
it immediately falls apart into water and carbon dioxide.
H2CO3 H2O
+ CO2
Because this reaction happens so quickly, the intermediate step
of carbonic acid is left out and two of the products of the reaction
are water and carbon dioxide.
As with hydroxide, the H+ comes associated with an anion
and the carbonate, with a cation. The anion and cation combine for
another product.
>> Example 10
Predict the products for the reaction of Fe2(CO3)3
and HNO3.
Solution:
The anion leftover is NO3. The cation
with carbonate is Fe3+. Worry about how many of each
there are when you balance.
Fe2(CO3)3 + HNO3 Fe(NO3)3
+ H2O + CO2
To balance, remember that you need two hydrogens for each carbonate
and that you get one water and one carbon dioxide for each carbonate.
You could also start balancing with the salt.
Fe2(CO3)3 + 6 HNO3 2
Fe(NO3)3 + 3 H2O + 3 CO2
>> Example 11
Predict the products of the following reactions.
- H2S + KOH

- LI2CO3 + HI

- CH3COOH+ NaHCO3

Solution:
- It's a hydroxide base, so water will be one product. The other
ions are K+ and S2, so the reaction is
H2S + 2 KOH 2
H2O + K2S
Don't forget to balance.
- It's a carbonate base, so water and CO2 are products.
The other ions are Li+ and I. Therefore
LI2CO3 + 2 HI 2
LiI + H2O + CO2
- It's a carbonate base, but it already has one hydrogen, so
it only needs one more instead of two to make the water and
CO2. The acid is organic, so only the hydrogen on
the end reacts. Remember that when you write ion compounds,
the cation comes first.
CH3COOH+ NaHCO3 H2O
+ CO2 + NaCH3COO
>> Predicting the Products of Precipitation
Reactions
Predicting the products of precipitation reactions is just a matter
of rearranging the cations and anions. The only tricky part is making
sure the ions have the appropriate ratio. If one of the reactants
is an acid, work with it as if it were H+ and an anion
(although this is not strictly true, it is how it reacts).
This method will get two products. Either both or neither might
be a precipitate. You must refer to the solubility rules to be sure.
Precipitates are insoluble salts.
>> Example 12
Predict the products of the following reactions. Identify the
precipitate, if any.
- H2S + MnSO4

- Hg2(NO3)2 + KCl

- NaC2H3O2 + CrI3

- Ba(OH)2 + H2SO4

- (NH4)3PO4 + CaBr2

Solution:
- The “pieces” that make up the reactants are: H+,
S2, Mn2+, and SO42.
So the reaction is
H2S + MnSO4 H2SO4
+ MnS
Sulfuric acid is a strong acid and will make ions in solution;
manganese(II) sulfide is an insoluble salt and the precipitate.
- The “pieces” that make up the reactants are Hg22+,
NO3 , K+, and Cl,
so
Hg2(NO3)2 + 2 KCl Hg2Cl2
+ 2 KNO3
Hg2Cl2 is the precipitate, since Hg22+
is an exception to the “chlorides are soluble” rule.
- The “pieces” that make up the reactants are Na+,
C2H3O2, Cr3+, and I, so
3 NaC2H3O2 + CrI3 3
NaI + Cr(C2H3O2)3
There are no precipitates in this reaction. Sodiums are always
soluble, and so are acetates.
- The “pieces” that make up the reactants are Ba2+,
OH, H+, and SO42,
so
Ba(OH)2 + H2SO4 BaSO4
+ 3 H2O
Barium sulfate is the precipitate. It is an exception to the
“sulfates are soluble” rule.
- The “pieces” that make up the reactants are: NH4+,
PO43, Ca2+, and Br, so
2 (NH4)3PO4 + 3 CaBr2 Ca3(PO4)2
+ 6 NH4Br
Calcium phosphate is the precipitate.
| C. Writing Net Ionic Equations |
With net ionic equations the key is to break the strong electrolytes,
and only the strong electrolytes, into the component ions. This
creates the total ionic equation. See the section on strong electrolytes
to identify the strong acids and soluble salts.
Any ion that is exactly the same on each side of the reaction is
a “spectator ion” and should be canceled, like simplifying
redox reactions. It may also be necessary to simplify the stoichiometric
coefficients at the end. When this is completed, you have the net
ionic equation.
>> Example 13
Write the balanced total and net ionic equations for the following
reactions.
- (NH4)3PO4 + CaBr2
Ca3(PO4)2
+ NH4Br
- NaC2H3O2 + CrI3
NaI
+ Cr(C2H3O2)3
- H2S + KOH
H2O
+ K2S
- LI2CO3 + HI
LiI
+ H2O + CO2
- HCl + Ca(OH)2
H2O
+ CaCl2
Solution:
- 2 (NH4)3PO4 3 CaBr2
Ca3(PO4)2
+ 6 NH4Br
6 NH4+ + 2 PO43
+ 3 Ca2+ + 6 Br Ca3(PO4)2
+ 6 NH4+ + 6 Br
2 PO43 + 3 Ca2+ Ca3(PO4)2
- 3 NaC2H3O2 + CrI3
3
NaI + Cr(C2H3O2)3
3 Na+ + 3 C2H3O2
+ Cr3+ + 3 I 3
Na+ + 3 I + Cr3+ + 3 C2H3O2
All ions cancel; there is no reaction.
- H2S + 2 KOH
2
H2O + K2S
H2S + 2 K+ + 2 OH 2
H2O + 2 K+ + S2
H2S + OH 2
H2O + S2
- LI2CO3 + 2 HI
2
LiI + H2O + CO2
2 LI2+ + CO32 + 2 H+
+ 2 I 2
Li+ + 2 I + H2O + CO2
CO32 + 2 H+ H2O
+ CO2
- 2 HCl + Ca(OH)2
2
H2O + CaCl2
2 H+ + 2 Cl + Ca2+ + 2 OH 2
H2O + Ca2+ + 2 Cl
2 H+ + 2 OH 2
H2O
H+ + OH H2O
>> View
the other Key Equations and Concepts in this chapter |